|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + tryprostatin_B
|
2.5.1.106
tryprostatin B synthase
|
–
|
BMK
|
| |
BRENDA:
BR50540
KEGG:
R10340
MetaCyc:
RXN-14418
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + deoxybrevianamide_E
|
2.5.1.109
brevianamide F prenyltransferase (deoxybrevianamide E-forming)
|
–
|
M
|
| |
BRENDA:
BR50669
KEGG:
R10456
MetaCyc:
RXN-14419
|
|
|
|
L-tryptophan + L-proline + 2 ATP <=> brevianamide_F + 2 AMP + 2 diphosphate
|
not assigned
|
–
|
K
|
| |
KEGG:
R10661
|
|
|
|
L-tryptophan + L-proline + ATP <=> brevianamide_F + ADP + phosphate + H+
|
6.3.3
|
–
|
M
|
| |
MetaCyc:
RXN-15642
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + (2S,3aR,8aR)-3a-(2-methylbut-3-en-2-yl)-1,2,3,3a,8,8a-hexahydropyrrolo[2,3-b]indole-2-carboxylic_acid
|
2.5.1.106
tryprostatin B synthase
|
–
|
|
| |
BRENDA:
BS437444
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + (5aS,6aR,11aR,13aS)-6a-(3-methylbut-2-en-1-yl)-2,3,6,6a,11,11a-hexahydro-1H-pyrrolo[1'''',2'''':4'',5'']pyrazino[1'',2'':1,5]pyrrolo[2,3-b]indole-5,13(5aH,13aH)-dione
|
2.5.1.106
tryprostatin B synthase
|
–
|
|
| |
BRENDA:
BS437445
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + 4-(3-methylbut-2-enyl)-cyclo-L-Trp-L-Pro
|
2.5.1.34
4-dimethylallyltryptophan synthase
|
–
|
|
| |
BRENDA:
BS437471
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + 7-(3-methylbut-2-enyl)-cyclo-L-Trp-L-Pro
|
2.5.1.109
brevianamide F prenyltransferase (deoxybrevianamide E-forming)
|
–
|
|
| |
BRENDA:
BS437472
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + cyclo-L-4-dimethylallyltryptophan-L-proline
|
2.5.1.34
4-dimethylallyltryptophan synthase
|
–
|
|
| |
BRENDA:
BS409309
|
|
